Technology

Rochester’s solar desalination brine-free system recovers lithium from seawater

A solar desalination brine-free system developed at the University of Rochester claims to produce fresh water from seawater while extracting nearly all dissolved salts as a solid rather than discharging concentrated liquid brine, and, in a separate related study, to recover roughly 50 per cent of the lithium contained in those leftover salts. The research, published across two journals, is still at proof-of-concept stage, and the team’s own papers acknowledge the devices tested so far are relatively small.

The claim is worth taking seriously precisely because conventional desalination carries well-documented problems. The United Nations estimates that 2.2 billion people do not have safely managed drinking water, and regions from California to the Middle East increasingly depend on desalination plants. Reverse osmosis and thermal distillation (the dominant industrial methods) both consume substantial energy and generate highly concentrated brine. When that brine re-enters the ocean, it raises local salinity and reduces oxygen levels, with consequences for marine organisms.

How the solar desalination brine-free system works

The approach from Rochester’s Institute of Optics centres on black metal panels treated with femtosecond lasers (pulses lasting one quadrillionth of a second) that reshape the metal’s surface at a microscopic level. That treatment gives the metal two properties the researchers consider essential: it absorbs sunlight extremely efficiently, and it becomes superwicking, meaning water spreads rapidly across the surface rather than pooling.

A thin layer of seawater is drawn across the panel’s active region. Solar heat drives evaporation, leaving salts and minerals behind. Rather than letting those deposits build up and eventually block the surface (the core failure mode in earlier solar desalination prototypes) the system uses microscopic grooves and the physics of the so-called coffee ring effect to push crystallised material toward untreated areas at the panel’s edges, described as the passive region.

The coffee ring effect will be familiar to anyone who has watched a spilled drink dry: as liquid evaporates, suspended particles migrate outward, leaving a concentrated ring at the edge. Chunlei Guo, a professor of optics and physics and a senior scientist at Rochester’s Laboratory for Laser Energetics who led the research, puts it plainly: ‘If you drop coffee on a surface, eventually the water evaporates and there’s a ring left at the outer edge that is the concentrated coffee particles. We use that same principle to advance the salts to the passive region.’

The real-seawater problem earlier systems struggled to solve

Guo’s team makes a point that undermines some earlier published results in this area. Many previous solar thermal desalination experiments used simplified artificial seawater, essentially water mixed with sodium chloride. Sodium chloride crystallises into a relatively porous, grainy structure that water can continue to penetrate, making the surface easier to self-clean. Real seawater, by contrast, contains magnesium, calcium and hundreds of other dissolved substances, some of which form hard, dense deposits comparable to the limescale inside a kettle or shower head, only far more concentrated.

The Rochester team says it tested its panels using actual seawater collected from the Pacific, Atlantic and Indian Oceans. In those experiments, the self-cleaning mechanism remained functional and the mineral accumulation in the passive region did not reduce the panel’s desalination efficiency, according to the paper published in the journal Light: Science & Applications.

A possible secondary market in lithium

The more commercially speculative claim sits in a companion study published in the Journal of Materials Chemistry A. There, the same team reports that nanoparticles made from hydrogen titanate, embedded in the grooves of the superwicking panels, can selectively isolate lithium from the mixture of salts collected after desalination. Using samples from Great Salt Lake, the researchers say they recovered approximately 50 per cent of the lithium present.

Guo frames the motivation in terms of the environmental costs of conventional lithium mining: ‘Mining lithium from the earth has proven to be very taxing from an energy and environmental standpoint, so pulling lithium directly from saltwater could be a very important future route.’ Whether a 50 per cent recovery rate would be commercially viable at scale is not addressed in the papers reviewed here.

The research was funded by the National Science Foundation, the Bill & Melinda Gates Foundation, and Worldwide Universities Network. The team describes the basic design as inherently scalable, but the path from small proof-of-concept devices to industrial desalination infrastructure is long, and no timeline for that transition is given.

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Alan Cartwright

Alan Cartwright spent twelve years in academic research before he started writing for a wider audience. He did a PhD in biochemistry, held postdoctoral positions at two Russell Group universities, and spent three years on a public engagement fellowship before realising he was better at explaining science than producing it. He writes about scientific research, health claims, evidence policy, and the gap between what a study actually shows and what the headline says it shows. He has peer-reviewed enough papers to know that 'further research is needed' is the most honest sentence in science. Alan lives in Oxford. He reads preprints before press releases and considers this the correct order of operations.

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